The game kicks off at 2pm with admission £5 adults and £3 concessions.
It is a key event as part of Marine's 125th anniversary celebrations, which last Saturday saw Dulwich Hamlet visit the Marine Travel Arena.
The Mariners link up with Liverpool FC also sees them staging a 125-year dinner in the Beautiful Game Suite at Anfield on Friday October 4.
Chairman Paul Leary said: “I would like to thank Liverpool FC for agreeing to send their Under 23 team this coming Sunday as part of our 125 Anniversary celebrations. This is a really special occasion for all connected with Marine Football Club and I look forward to meeting the Liverpool staff, players and fans visiting us this coming Sunday.
“I expect there to be a very good attendance for the game and urge fans to arrive early. The game kicks off at 2pm and turnstiles will open at 1pm with the Clubrooms open to all fans from midday.”
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