Scrivens, 24, has already spent time on loan with the Gladiators from Guiseley earlier this season.
Manager Steve Kittrick said: "I'm really delighted to get this one over the line, Sam did ever so well with us earlier in the season and I'm sure all of our fans will be pleased to see him back in a Matlock shirt."
Scrivens played a key role for Penistone Church who finished second in the Toolstation NCEL league last season. He featured for Chesterfield in their pre season game at the Proctor Cars Stadium.
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